Thus, regarding temperature, the water in the cylinder is divided into two distinct parts:
The normal and anomalous behavior of water with temperature is also clear from the time-temp. graph.
Q.26: Define thermal expansion of gases?
Ans: THERMAL EXPANSION OF GASES:
Like solids and liquids, the gases also expand on heating, but gases expand to a greater extent. Their co-efficient of expansion is very high.
Q.27: State and explain Boyle’s Law?
Ans: STATEMENT:
According to Boyle’s Law,
“The volume of a given mass of a gas is inversely proportional to the pressure, if the temperature is kept constant.”
Derivation:
Consider we have a gas having the volume “v” and pressure “P”, and “T” is the temperature which is kept as a constant quantity. Therefore, mathematically,
v∝P1
Or
v=Constant×P1
Or
Pv=Constant
For the initial stage, we can say that:
P1v1=Constant (i)
For the final stage, we can say that:
P2v2=Constant (ii)
By comparing equation (i) and equation (ii), we have:
P1v1=P2v2
The value of constant in Boyle’s Law depends on the mass of the gas, then
Pv∝m
mPv=Constant
If P1,v1 and m1 are the initial pressure, volume, and mass, and P2,v2 and m2 are the final pressure, volume, and mass, then:
m1P1v1=m2P2v2
The graph between pressure and volume is a hyperbola showing the inverse relation between them.
Graphical Representation of Boyle’s Law:
A graph, plotted between pressure and volume, is a hyperbola as shown in the figure. The graph shows that the volume varies with pressure in such a way that the product is constant.
Q.28: State and explain Charles’s Law?
Ans: STATEMENT:
According to Charles’s Law:
“The volume of a given mass of a gas in a closed system is directly proportional to the absolute temperature, if pressure is kept constant.”
Consider we have a gas having the volume “V” at temperature “T”, when pressure is kept constant.
Mathematically,
V∝T
Or
V=Constant×T
Or
TV=Constant
At initial stage, we have:
T1V1=Constant— (i)
At final stage, we have:
T2V2=Constant— (ii)
By comparing equation (i) and equation (ii), we have:
T1V1=T2V2
Graphical Representation of Charles’s Law:
As the volume varies directly with temperature, the graph plotted between volume and temperature is a straight line.
Q.29: What is absolute zero?
Ans: ABSOLUTE ZERO:
The temperature of -273°C, which is equal to 0°K on the absolute scale of temperature, is called absolute zero. Thus, according to Charles’s law, absolute zero is the temperature at which the volume of a gas should be zero. Kinetic Theory provides a better definition of absolute zero, according to which this is the temperature at which all the molecules of a material body cease to move.
Q.30: Derive the General Gas Equation?
Ans: GENERAL GAS EQUATION:
By combining Boyle’s law and Charles’s law into one equation, we get the general gas equation.
According to Boyle’s Law:
V∝P1— (i)
According to Charles’s Law:
V∝T— (ii)
On combining equation (i) and equation (ii), we have:
V∝PT
Or
V=Constant×PT
Or
TPV=Constant
If P1,V1, and T1 are the initial pressure, volume, and temperature, and P2,V2, and T2 are the final pressure, volume, and temperature, then:
T1P1V1=T2P2V2— (iii)
The volume of the constant depends on the mass of the gas expressed in moles. For one mole of the gas, the constant is called the universal gas constant, which is denoted by R. The S.I. unit value of R is 8.3145 J/mol K. For “n” moles of the gas, the value of the constant is nR.
Thus,
TPV=nR
Hence,
PV=nRT
Q.31: What are the units of heat?
Ans:
These are the following units of heat in different systems:
Calorie:
- The amount of heat required to raise the temperature of one gram of water by 1°C.
Kilo Calorie:
- The amount of heat required to raise or fall the temperature of one kilogram of water by 1°C.
British Thermal Unit (B.T.U):
- The amount of heat required to raise the temperature of one pound of water by 1°F.
Joule:
- It is the amount of heat required to raise the temperature of 42001 kg of pure water at standard pressure from 14.5°C to 15.5°C.
Q.32: What is heat capacity? Write its formula and units?
Ans: HEAT CAPACITY:
The amount of heat or quantity of heat required to raise the temperature of a body through 1 K.
Formula:
Heat Capacity=ΔTΔQUnit:
- The unit of Heat Capacity is J/°C or J/K.
Q.33: Define Specific Heat Capacity? Write its formula and unit?
Ans: SPECIFIC HEAT CAPACITY:
The amount of heat required to raise the temperature of unit mass of the substance by 1 K.
Formula:
C=mΔTΔQWhere “m” stands for mass of the substance, ΔQ stands for amount of heat, and ΔT stands for change in temperature.
Unit:
- The unit of specific heat capacity is J/kg K or J kg−1 K−1.
Q.34: Write down the factors on which specific heat capacity depends?
Ans: FACTORS:
- It depends on the nature of the substance and is entirely independent of its mass and the rise in temperature.
- If “c” is small for the substance, the heat needed will also be small.
- If “c” is large, the heat needed will also be large under similar conditions of mass and rise in temperature for all substances.
Q.35: Derive a relation between Heat Capacity and Specific Heat Capacity?
Ans:
The heat capacity depends on the mass of the body and its material, whereas specific heat capacity simply depends on the nature of the body material. Heat capacity gives total heat content per degree rise of temperature of a body, and specific heat capacity is the heat per unit mass per degree rise of temperature of the object.
As we know that:
C=ΔTΔQ— (i)
And
C=mΔTΔQ— (ii)
Or
C=mc— (iii)
Now by comparing equation (i) and equation (iii):
C=mc
Q.36: State the law of Heat Exchange?
Ans: LAW OF HEAT EXCHANGE:
According to this law, when two bodies are brought in thermal contact, they exchange heat irrespective of the temperature. If two bodies of different temperature are brought in contact, the body of higher temperature will lose more heat and give that heat to the body of lower temperature, and the body of lower temperature will lose less heat and give that heat to the body of higher temperature. Thus, there is a net loss of heat from the body of higher temperature and net gain by the body of lower temperature.
For an isolated system, the law of heat exchange is:
Heat lost by the hot body=Heat gained by the cold body
Q.37: Describe the method for measurement of specific heat capacity?
Ans: METHOD:
In this method, a certain amount of water of known mass and temperature is kept in a vessel called a calorimeter. Usually, we fill two-thirds of the calorimeter with water at room temperature. A known mass of the substance (solid), whose specific heat is to be determined, is heated through a certain temperature and then put into the water contained in the calorimeter. According to the law of heat exchange, the heat is lost by the hot substance and gained by the water and calorimeter. We take the following observations:
Observations:
- Mass of the calorimeter and stirrers = m1kg
- Mass of calorimeter + stirrer + H2O = m2kg
- Temperature of the calorimeter + H2O = t1°C
- Temperature of the substance = t2°C
- Temperature of mixture = t3°C
- Mass of Calorimeter + stirrer + H2O + substance = m3kg
- Mass of H2O = (m2−m1)kg
- Mass of substance = (m3−m2)kg
- Specific heat of H2O = C=4200J/kg K
- Specific heat of Calorimeter made of copper = C1=390J/kg K
- Specific heat of substance = C2
Calculation:
Now we calculate the heat lost and gained separately.
By using the law of heat exchange:
Heat lost=Heat gained
C2(m1−m2)(t2−t3)=C1m1(t3−t1)+C(m2−m1)(t3−t1)
C2=(m1−m2)(t2−t3)C1m1(t3−t1)+C(m2−m1)(t3−t1)
Q.38: What is Latent Heat? Write its formula and unit?
Ans: LATENT HEAT:
It is the amount of heat required to change the state of a substance without any change in temperature.
Formula:
L=mΔQ
Where “L” stands for latent heat, ΔQ stands for the amount of heat, and “m” stands for the mass of the substance.
Unit:
The unit of latent heat is J/kg or J kg−1.
Q.39: Define and explain the latent heat of fusion of ice?
Ans: LATENT HEAT OF FUSION OF ICE:
The quantity of heat required to transform one kilogram of a solid completely into liquid at its melting point is called Latent Heat of melting or fusion.
Latent heat of ice is 3.36×105J/kg. It means that 3.36×105 J of heat is required to transform one kg of ice into water at 0°C.
Explanation:
For example, if a piece of ice at 0°C is heated, its temperature does not rise until the whole of the ice has been melted to water at the same temperature (0°C). Here the heat energy added is used up in loosening the bonds between the molecules. The result is that the molecules begin to vibrate vigorously. The vibrational amplitude of the molecules becomes so large that the bonds between them break and the molecules become free. Those molecules thus form water in which they move about freely.
Q.40: Define and explain Latent Heat of Vaporization?
Ans: LATENT HEAT OF VAPORIZATION:
The amount of heat required to transform the mass of one kg of liquid completely into gas at its boiling point is called the Latent Heat of boiling or vaporization.
The latent heat of water is 2.26×106J/kg. It means that one kg of water requires 2.26×106 J of heat to change into gas at 100°C.
Explanation:
The latent heat of vaporization is used up to separate the close liquid molecules. Latent heat of vaporization is used to overcome the strong intermolecular forces of attraction of the liquid molecules.
Q.41: Write down the laws of fusion?
Ans: LAWS OF FUSION:
Laws of fusion are as follows:
- Every substance changes its state from solid to liquid at a particular temperature (at normal pressure).
- During the change of state, the temperature remains constant.
- One kilogram of every solid substance needs a definite quantity of heat energy to change its state from solid to liquid. It is called the latent heat of fusion of the substance.
- Mostly substances show an increase in their volumes on melting (for example, wax, ghee), while a few substances show a decrease in their volumes on melting (ice).
- Melting points of those substances which show a decrease in their volumes on melting are lowered with the increase of pressure, whereas melting points of those substances which show an increase in their volumes are increased with the increase of pressure.
Q.42: What is the transmission of heat? Explain the different modes of transmission of heat with the help of examples?
Ans: TRANSMISSION OF HEAT:
Heat travels from hot body to cold body or from one place to another because of the difference in temperature.
There are three different modes of transfer:
- Conduction
- Convection
- Radiation
CONDUCTION:
Definition:
Conduction is the process in which heat is transferred by the interaction of atoms and molecules.
Explanation:
- When a body is heated, its temperature rises. Due to the rise in temperature, the average kinetic energy of atoms increases.
- Hence, the atoms begin to vibrate with greater amplitude with the rise of temperature about their mean positions.
- This results in the collision of atoms.
- The heat absorbed by an atom is transferred to the neighboring atoms through collision.
Experiment:
- A long metal bar is covered with a thin layer of wax at one end.
- The wax-coated end is heated by placing it under a flame. This end absorbs heat energy, and as a result, the wax begins to melt. Sooner, the bar gets hot.
CONVECTION:
Definition:
Convection is the transmission of heat due to the actual movement of molecules of a substance from one place to another.
Explanation:
- The fluid receives heat directly from the source and gets heated. It expands, becomes lighter, and therefore rises up. The circulation of fluid sets up convection currents. The same process holds in the boiling of water, which is taken in an electric kettle. The heater of the kettle is normally placed near the bottom of the kettle so that as the water at the bottom is heated, it expands and gets lighter. Being lighter, it rises up while the cooler section of water, being denser, moves down and is heated.
- This process is repeated due to convection currents being set up until the whole water reaches the boiling point.
Examples Showing Transfer of Heat in Convection:
Example 1:
- Take a flask containing water. Now add a large crystal of KMnO4 to the water. The flask is heated, and colored streaks of water rise up. It is because the water at the bottom gets heated, expands, and becomes lighter, hence going up along the sides of the vessel. Water from the sides of the flask, being somewhat denser, reaches the bottom, gets heated, and rises up, thus forming colored streaks as shown in the figure.
Example 2:
- Take a candle and fix it at the bottom of a cylinder, as shown in the figure. Light the candle. It will be found that the flame becomes weaker and weaker and finally gets extinguished. This is due to the fact that by burning, the air in the cylinder gets heated, expands, and is pushed out. There is no fresh supply of air for the burning of the candle. Now take a cardboard and hold it inside the cylinder, dividing the space above the candle into two parts. Again, light up the candle. It will continue to burn.
Here, the air above the flame gets heated and goes up through the other side, forming convection current, and so the candle continues to burn.
RADIATION:
Definition:
Radiation is the process of heat transmission in which heat energy is transferred from one place to another in the form of waves without affecting the medium.
Explanation:
All objects emit energy at all temperatures from their surfaces.
Example:
A hot piece of metal gives off light. Its color depends on the temperature of the metal, going from red to yellow to white as it becomes hotter and hotter. The light emitted corresponding to different colors is a part of electromagnetic waves. At room temperature, most of the radiation is found in the infrared region. Light of every color (from infrared to ultraviolet), radio and TV waves, microwaves, and X-rays are all electromagnetic waves. The difference lies in their frequencies and wavelengths.
Q.43: Define thermal conductivity? Derive its formula and write down the factors and units of thermal conductivity?
Ans: THERMAL CONDUCTIVITY:
Definition:
The ability of a substance to conduct heat is called thermal conductivity.
This ability is the measure of thermal conductivity of a substance, which is the thermal property of a substance.
Experiment:
To find thermal conductivity, we consider a solid slab of thickness “ΔL” and face area “A”. Its two faces are maintained at temperatures T1 and T2. The amount of heat “ΔQ” flowing through the slab in time “ΔT” depends upon the following observations:
- Change of temperature: ΔT=T2−T1 (where T2>T1)
- Face area: A
- Time for which heat flows: ΔL
Now, we can observe that:
Or,
“K” is a constant of proportionality called the coefficient of thermal conductivity. Its value depends on the material of the slab.
If A=1m2, ΔL=1m, ΔT=1°C, and Δt=1s,
Then:
Unit of Thermal Conductivity:
ΔL=1m
A=1m2
ΔT=1°C
Δt=1s
Then,
K=AΔT⋅ΔtΔQ×ΔL
K=m2⋅C⋅sJoule⋅m
K=m⋅C⋅sJ
K=JC−1m−1s−1
Factors of Thermal Conductivity:
- It depends on the nature of a substance.
- It is large for metals and small for non-metallic solids, liquids, and gases.
Q.44: What is a thermo flask? Write down its construction and working?
Ans: THERMO FLASK:
Definition:
A thermo flask is a device where all the three modes of transfer of heat are applied.
Construction:
- It consists of a double-walled glass bottle.
- The inner surface of the outer wall and outer surface of the inner wall are lightly polished.
- The space between the walls is evacuated and sealed.
- The whole system is enclosed within a metal case, which is provided with a cork at the bottom and a pad of felt at the neck for safety, as shown in the figure.
- Glass is a poor conductor of heat, whereas air, cork, felt, etc., are bad conductors of heat.
- Hence, they prevent any loss of heat due to conduction.
Working:
- When a hot liquid is kept in the bottle, it remains hot for a long time.
- Any heat radiation coming from the hot liquid is reflected back from the inner surface of the outer wall.
- The heat from the liquid cannot flow out through conduction and convection because of the empty space between the walls.
Q.45: What are the practical applications of conduction of heat?
Ans: PRACTICAL APPLICATIONS OF CONDUCTION OF HEAT:
Ice Box:
- An ice box has a double wall, made of tin or iron. The space between the two walls is filled with cork or felt, which are poor conductors of heat. They prevent the flow of outside heat into the box, thus keeping the ice from melting.
Woolen Clothes:
- Woolen clothes have fine pores filled with air. Air and wool are bad conductors of heat. Thus, the heat from the body does not flow out to the atmosphere. This keeps the body warm in winter.
Double Doors:
- In cold countries, windows are provided with double doors. The air in the space between the two doors forms a non-conducting layer, and so heat cannot flow out from inside the room.
Tightly Fitted Stopper:
- When a stopper, fitted tightly to the bottle, is to be removed, the neck of the bottle is gently heated. It expands slightly on heating. Since glass is a bad conductor of heat, the heat does not reach the stopper. Thus, it can be removed easily.
Davy’s Safety Lamp:
- It is one of the most important applications of conduction of heat. The principle of Davy’s safety lamp can be understood from this example:
- A wire gauze is placed over a Bunsen burner. The gas coming from the burner is lit above the wire gauze, as shown in the figure. A flame appears at the top surface of the wire gauze.
- The gas coming out from the burner below the wire gauze does not get sufficiently hot for ignition.
- The reason is that the wire gauze conducts away the heat of the flame above it, so the temperature at the lower surface of the gauze does not reach the ignition point.
- In Davy’s safety lamp, a cylindrical metal gauze of high thermal conductivity surrounds the flame, as shown in the figure.
- When this lamp is taken inside a mine, the explosive gases present in the mine are not ignited because the wire gauze in the form of a cylinder conducts away the heat of the flame of the lamp.
- The result is that the temperature outside the gauze remains below the ignition point of the gases. In the absence of the wire gauze, the gases outside could explode.
Q.46: What are the practical applications of convection of heat?
Ans: PRACTICAL APPLICATIONS OF CONVECTION OF HEAT:
Ventilation:
- From a health point of view, every living room of a building should be provided with ventilators near the ceiling. Due to the respiration of the persons sitting or sleeping in the room, the air in the room gets warmer and hence is less dense. It rises up and goes outside through the doors and windows. Thus, a convection current of air is maintained.
Trade Winds:
- At the equator, the surface of the earth gets heated more than at the poles. This results in the movement of warm air from the equator to the poles, while cold air moves towards the equator. Because of the rotation of the earth (from west to east), the air in the northern hemisphere seems to be coming from the northeast instead of from the north. In the southern hemisphere, the air from the South Pole appears to be coming from the southwest. These winds are called trade winds because in old days these winds were used by traders for sailing their ships.
Land and Sea Breeze:
- Land is a better conductor of heat than water. Hence, in the daytime,
The land gets hotter than water in the sea. The air above the land becomes warm and rises up, being lighter, and somewhat cold air above the sea surface moves towards the seashore. This is known as a sea breeze. In the night, the land cools faster than seawater. The seawater uses tip and cold air from sand moves towards the sea. This is a land breeze.
Q.47: Write down the practical application of heat radiation?
Ans: DIFFERENTIAL AIR THERMOSCOPE:
It is an important application of radiation heat.
Construction:
- It consists of two radical glass bulbs A and B, which are connected by a narrow glass tubing having the shape of a U-tube.
- The tube consists of sulfuric acid. The space above the levels of the acid in the two arms of the tube contains air.
- When the bulbs are at the same temperature, there is no difference in the level of the acid in the limbs.
- The bulb A is coated with lamp black so that it may completely absorb the heat radiation falling on it.
Working:
- Now the bulb A is exposed to heat radiation. It absorbs the radiation falling on it. As a result, the air in bulb A gets heated, expands, and presses down the acid in the limb. Thus, we have a difference in the level of the liquid in the two limbs.
Advantages of Thermoscope:
- It is very sensitive and can detect radiation of very weak intensity, for example, radiation coming from a distant candle.
BOY’S RADIOMICROMETER:
It is also a very sensitive device.
Construction:
- It is a combination of a moving coil galvanometer and a thermocouple.
- It consists of a single loop of silver or copper wire A.
- The lower ends of the wire are soldered to a copper disc, which is coated with lamp black.
Working:
- The disc is exposed to heat radiation, and as a result, thermo-electric current is produced in the couple made of bismuth and antimony and begins to flow in the wire A. Hence, we get a current in the galvanometer. The deflection produced in the galvanometer can be measured by using a lamp and scale arrangement.
Advantages of Boy’s Radiomicrometer:
- It can detect heat radiation of very weak intensity, for example, radiation coming from a distant candle.
Q.48: Write down the difference between heat and temperature?
Heat | Temperature |
---|
Heat is energy that flows from a high-temperature object to a low-temperature object. | Temperature is the degree of hotness or coldness. |
Heat of a body is the sum of all kinetic and potential energies of all molecules constituting the body. | Temperature of a body is the average kinetic energy of its molecules. |
Heat can be measured by a calorimeter. | Temperature of a body is measured by a thermometer. |
S.I. Unit of heat is Joule. | S.I. Unit of temperature is Kelvin (K), but it is also measured on “°C” or “°F” scales. |
Q.49: Write down the difference between heat capacity and specific heat capacity?
Heat Capacity | Specific Heat Capacity |
---|
It is defined as the quantity of heat required to produce unit temperature change. | It is the quantity of heat required to change the temperature of unit mass of a substance by one degree Celsius. |
Its S.I. Unit is J/K. | Its S.I. Unit is J/kg K. |
Its value depends on mass and nature of the substance. | Its value depends on the nature of the substance. |
Q.50: Write down the difference between conduction and convection?
Conduction | Convection |
---|
It is the transmission of heat from one part of the body to another part by interaction of electrons and molecules. | It is the transmission of heat due to actual movement of molecules of the substance from one place to another. |
It occurs in solids. | It occurs in liquids and gases. |
During conduction, molecules do not change their average position. | During convection, molecules change their position. |
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